The relationship between thermodynamics and the toxicity of gadolinium complexes

WP Cacheris, SC Quay, SM Rocklage - Magnetic resonance imaging, 1990 - Elsevier
Rocklage, SaluBMA, Joan Carvalho for synthesizing and formulating … NMR (D,O): 6 2.46 (s,
8H), 3.55 (s, 4H), 7.10 (m, 4H), 7.55 (t, J= 12.5 Hz, 2H), 8.25 (d, J… 2.40 x 1O-3 M 2.46 x 10-s M …

Tungsten (VI) neopentylidyne complexes

…, J Sancho, JH Wengrovius, SM Rocklage… - …, 1982 - ACS Publications
Several years ago we discovered that the reaction be-tween WC16 and 6 equiv of
neopentyllithium in diethyl ether produces the volatile yellow neopentylidyne complex, W (CCMe3)(…

Preparation and characterization of active niobium, tantalum and tungsten metathesis catalysts

R Schrock, S Rocklage, J Wengrovius… - Journal of Molecular …, 1980 - Elsevier
… In the past few years, we have been s~dying alk-ylidene … We will, however, ~e elomenfal
analyc~s results and NMR … We should note that the s~,m of the amounts of all products …

Preclinical evaluation of MnDPDP: new paramagnetic hepatobiliary contrast agent for MR imaging.

G Elizondo, CJ Fretz, DD Stark, SM Rocklage, SC Quay… - Radiology, 1991 - pubs.rsna.org
Manganese(II)-N,N'-dipyridoxylethylenediamine-N,N'-diacetate-5,5'-bis (phosphate) (MnDPDP)
is a paramagnetic complex designed for use as a hepatobiliary agent. The T1 relaxivity …

Manganese (II) N, N'-dipyridoxylethylenediamine-N, N'-diacetate 5, 5'-bis (phosphate). Synthesis and characterization of a paramagnetic chelate for magnetic …

SM Rocklage, WP Cacheris, SC Quay… - Inorganic …, 1989 - ACS Publications
… parameter defined as (4/3)[o2/3(l,l) + b20(2,2) + ¡30(3,3) + ab(cos 7)5(1,2) + ac(cos 0)0(1,3)
+ bc(cos a)0(2,3), where a, b, and c are real cell parameters and 0(ij) are anisotropic 0’s. …

Multiple metal-carbon bonds. 19. How niobium and tantalum complexes of the type M (CHCMe3)(PR3) 2Cl3 can be modified to give olefin metathesis catalysts

SM Rocklage, JD Fellmann, GA Rupprecht… - Journal of the …, 1981 - ACS Publications
… In this case, as well as the above, we do not knowwhat the major chain-terminating
reaction(s) is (are). However, we suspect that the intermediate propylidene and ethylidene …

Hepatobiliary MR imaging: first human experience with MnDPDP.

…, DD Stark, PT Leese, A Pfefferbaum, SM Rocklage… - Radiology, 1991 - pubs.rsna.org
The first human MR imaging results for the hepatobiliary contrast agent manganese(II)N,N'-dipyridoxylethylenediamine-N,N'-diacetate
5,5'-bis(phosphate) (MnDPDP) are reported. …

Gadolinium complexation by a new diethylenetriaminepentaacetic acid-amide ligand. Amide oxygen coordination

…, KN Raymond, SC Quay, SM Rocklage - Inorganic …, 1990 - ACS Publications
We have undertaken the preparation and characterization of novel lanthanide complexes for
evaluation as constrast agents for magnetic resonance imaging (MRI). Contrast agents are …

Preparation of organoimido and. mu.-dinitrogen complexes of tantalum and niobium from neopentylidene complexes

SM Rocklage, RR Schrock - Journal of the American Chemical …, 1982 - ACS Publications
… I5N spectra were run at 9.04 MHz with a pulse delay of ~5 s and are referenced as
downfield shifts from liquid NH3. Infrared spectra were obtained on a Perkin-Elmer 283B …

[PDF][PDF] Detection of small-molecule enzyme inhibitors with peptides isolated from phage-displayed combinatorial peptide libraries

…, J Kranz, P Gallant, J Zhang, SM Rocklage… - Chemistry & biology, 2000 - cell.com
… 2–5 moles of biotin per mole of target protein following the manufacturer’s protocol. The
extent of biotinylation was determined using HABA according to the manufacturer’s instructions. …